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This course provides a comprehensive understanding
of macromolecule synthesis, growth quantification, and the
translation of synthetic strategies into functional
materials. Students explore all major polymerization
methods; step-growth, free-radical (bulk, solution,
suspension, emulsion, controlled/living), ionic,
coordination, ring-opening, and copolymerization;
while applying kinetic and thermodynamic models
(Carothers, radical rate laws, Mayo–Lewis, gelation theory)
to predict conversion, molecular weight distribution, and
architecture. Structure–property relationships including
glass-transition behavior, crystallinity, crosslink density,
and network formation are integrated throughout
reaction design discussions. The course emphasizes
converting mechanistic insights into practical process
conditions that achieve targeted thermal, mechanical, or
functional performance. Students develop hands-on expertise
through integrated laboratory and analysis modules,
synthesizing representative polymers, monitoring real-time
reactions, and characterizing products using modern
analytical techniques. Upon completion, participants can
formulate synthetic pathways, manipulate reaction
variables to control macromolecular architecture, and
connect chemical structure to end-use properties, essential
skills for advanced materials science and nano-engineering
research.
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