Thermodynamics (ENS 202)

2024 Fall
Faculty of Engineering and Natural Sciences
Engineering Sciences(ENS)
3
6
Mehmet Yıldız mehmet.yildiz@sabanciuniv.edu,
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English
Undergraduate
NS102
Formal lecture,Recitation
Interactive,Learner centered,Communicative,Discussion based learning,Task based learning
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CONTENT

Fundamental concepts and mathematical tools ; thermal equilibrium; Zeroth Law and definition of temperature; equations of state; First and Second Laws; thermodynamic potentials (enthalpy, Helmholtz, Gibbs) and the Maxwell relations; first order phase transitions; critical phenomena; Third Law, negative temperatures; introduction to statistical mechanics.

OBJECTIVE

To equip the students with a basic understanding of equilibrium, both from a macroscopic and a microscopic viewpoint, so that they can (i) perform the energy balance for a system and analyze the energy transfer processes in the system; (ii) interrelate various thermodynamic functions so that hard-to-measure properties may be determined through the measurable ones; (iii) develop a basic understanding of phase behavior.

LEARNING OUTCOMES

  • State and explain general concepts used in thermodynamics including the system and its surroundings, mechanisms of energy transfer; state versus path function.
  • Interpret the basic assumptions of the ideal gas law and illustrate how the van der Waals equation of state rectifies these assumptions to lead to a gas <-> liquid phase transition behavior and the critical point.
  • Using published data, such as heat capacity, calculate the internal energy, enthalpy changes of a system with respect to a reference state.
  • Apply the first law of thermodynamics by performing a detailed balance of energy transfer for a variety of real systems involving thermal energy, calculate efficiency in energy conversion
  • Define second law of thermodynamics and using published data calculate the entropy change of a system and surroundings
  • Write the entropy rate balance for control values and calculate the entropy production
  • Define and calculate the Gibbs and Helmholtz free energy changes in various systems using Maxwell's relations, write the differential forms of state functions
  • Define chemical potential and relate it to change in Gibbs energy and identify reversibility and spontaneity in changes towards equilibrium.
  • Describe the physical, structural, and thermodynamic properties of equilibrium phases and phase transformations in single and two-component systems
  • Determine the changes in thermodynamic properties in ideal, non-ideal, dilute, and in regular solutions
  • Draw P-V and T-V diagram of pure substances, determine the phase of a substance at different conditions
  • Calculate the activities and activity coefficients for real solutions
  • Apply the Lever Rule to determine the phase composition in a multi-phase field;
  • Define the ideal thermodynamic cycles for gas and gas-vapor systems and calculate the thermal efficiency

PROGRAMME OUTCOMES


1. Understand the world, their country, their society, as well as themselves and have awareness of ethical problems, social rights, values and responsibility to the self and to others. 2

2. Understand different disciplines from natural and social sciences to mathematics and art, and develop interdisciplinary approaches in thinking and practice. 3

3. Think critically, follow innovations and developments in science and technology, demonstrate personal and organizational entrepreneurship and engage in life-long learning in various subjects; have the ability to continue to educate him/herself. 4

4. Communicate effectively in Turkish and English by oral, written, graphical and technological means. 4

5. Take individual and team responsibility, function effectively and respectively as an individual and a member or a leader of a team; and have the skills to work effectively in multi-disciplinary teams. 4


1. Possess sufficient knowledge of mathematics, science, fundamental engineering, computational methods and program-specific engineering topics; use theoretical and applied knowledge of these areas in complex engineering problems. 5

2. Identify, define, formulate and solve complex engineering problems while considering the UN Sustainable Development Goals; choose and apply suitable analysis, design, estimation/prediction and modeling methods for this purpose. 5

3. Develop, choose and use modern techniques and tools that are needed for analysis and solution of complex problems faced in engineering applications; use information technologies effectively. 5

4. Have the ability to design a complex system, process, instrument or a product under realistic constraints and conditions, with the goal of fulfilling creative current and future requirements. 3

5. Use research methods, including conducting literature reviews, designing experiments, performing experiments, collecting data, analyzing results, and interpreting results, to investigate complex engineering problems or discipline-specific research topics. 3

6. Possess knowledge of business practices such as project management, risk management, change management, and economic feasibility analysis; awareness on entrepreneurship and innovation. 2

7. Possess knowledge of impact of engineering solutions on society, health and safety, the economy, sustainability, and the environment within the framework of the UN Sustainable Development Goals; awareness on legal outcomes of engineering solutions; awareness of acting impartially and inclusively without any form of discrimination; act in accordance with ethical principles, possessing knowledge of professional and ethical responsibilities. 4

8. Communicate effectively, both orally and in writing, on technical subjects, considering the diverse characteristics of the target audience (such as education, language, and profession). 3

ASSESSMENT METHODS and CRITERIA

  Percentage (%)
Final 30
Midterm 40
Quiz 10
Assignment 5
Participation 5
Homework 10

RECOMENDED or REQUIRED READINGS

Textbook

-- Thermodynamics, Statistical Thermodynamics & Kinetics, 3/E
Thomas Engel, Philip Reid
-- Thermodynamics by Çengel & Boles

Readings

-- Thermodynamics of Materials, Vol. I by D.V. Ragone (ISBN 0-471-30885-4)
-- Physical Chemistry by Atkins & de Paula